Metals in Carbohydrate Synthesis

Name: Metals in Carbohydrate Synthesis
Brand: Sudwestdeutscher Verlag Fur Hochschulschriften AG
SKU: 9783838150895
Price: 1337 CZK
Availability: InStock

Indium and Titanium mediated Chain Elongations of Chiral Pool Building Blocks

Autor: Albler Christopher

Jazyk:

Vazba: Brožovaná

Vydavatel: Sudwestdeutscher Verlag Fur Hochschulschriften AG

Dostupnost: Skladem u dodavatele

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This book describes two different projects associated with the chemical (de novo) synthesis of rare...

Informace o knize

Autor

Albler Christopher

Jazyk

Angličtina

Vazba

Kniha - Brožovaná

Vydáno

2015

Stránek

196

EAN

9783838150895

ISBN

3838150899

Enbook ID

09324287

Vydavatel

Sudwestdeutscher Verlag Fur Hochschulschriften AG

Hmotnost

295

Rozměry

152 x 229 x 11

Kompletní popis

This book describes two different projects associated with the chemical (de novo) synthesis of rare and unnatural carbohydrates from readily available starting materials. After a comprehensive introduction to indium chemistry and stereoselective aldol reactions, two new methodologies are presented which complement the synthetic arsenal available to the carbohydrate chemist. The indium mediated allylation of unprotected carbohydrates was applied in the synthesis of acetamido-heptoses and octoses which are constituents of the aminoglycoside antibiotics Apramycin and Destomycin. Furthermore, a new approach for the incorporation of fluorine into carbohydrates is described. Amino acid building blocks were chain-elongated via a titanium mediated aldol addition, finally furnishing amino-, fluoro-functionalised pentoses and hexoses. These compounds are of high interest not only concerning their potential antimicrobial activity but also their usefulness in elucidating fundamental biological processes such as antigen-antibody aggregation.

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Metals in Carbohydrate Synthesis

Indium and Titanium mediated Chain Elongations of Chiral Pool Building Blocks

Informace o knize

Kompletní popis

Mohlo by vás zajímat

Zákaznicí kteří koupili tuto knihu koupili také